749862-73-5Relevant articles and documents
Formation and utility of azasilacyclopentadienes derived from silacyclopropenes and nitriles
Anderson, Laura L.,Woerpel
supporting information; experimental part, p. 425 - 428 (2009/07/11)
(Chemical Equation Presented) The copper-catalyzed insertions of nitriles into the Si-C bonds of silacyclopropenes provide azasilacyclopentadienes, which can be converted to allylic amines after reduction and protodesilylation. The enamine functionality o
Formation and utility of oxasilacyclopentenes derived from functionalized alkynes
Clark, Timothy B.,Woerpel
, p. 9522 - 9523 (2007/10/03)
Oxasilacyclopentenes were shown to be synthetically useful masked allylic alcohols constructed in high yields and regioselectivities from terminal and internal alkynes. Several functional groups were shown to be tolerated utilizing silver-catalyzed silacy
