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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) is a complex organoruthenium compound featuring a diruthenium core with chloro and dimethylammonium ligands, as well as binaphthyl moieties with di-p-tolylphosphino groups. This sophisticated structure endows it with unique catalytic properties and potential applications in asymmetric synthesis.
Used in Catalyst Industry:
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) is used as a catalyst in asymmetric hydrogenation reactions for its ability to selectively reduce prochiral compounds, leading to the formation of enantiomerically pure products.
Used in Takasago Ligands and Complexes Industry:
In the field of Takasago Ligands and Complexes, Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) is utilized for its role in asymmetric reactions, where it can facilitate the selective formation of desired enantiomers, which is crucial for the synthesis of biologically active compounds and pharmaceuticals.

749935-02-2

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Basic information
1. Product Name: Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)
2. Synonyms: Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II);(R)-[(RuCl(T-BINAP))2(μ-Cl)3[NH2Me2];Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(di-p-tolylphosphino)-1,1μ-binaphthyl]diruthenate(II);Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-tolbinap)}2(μ- Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-tolbinap)}2(μ-Cl)3];[NH2Me2][(RuCl((R)-tolbinap))2(mu-Cl)3];(R)-[(RuCl(T-BINAP))2(μ-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((
3. CAS NO:749935-02-2
4. Molecular Formula: (CH3)2NH2+[C96H80Cl5P4Ru2]−
5. Molecular Weight: 1787.11
6. EINECS: N/A
7. Product Categories: Ru
Chemical Properties
1. Melting Point: >100°C
2. Boiling Point: N/A
3. Flash Point: N/A
4. Appearance: brown/Powder
5. Density: N/A
6. Refractive Index: N/A
7. Storage Temp.: 2-8°C
8. Solubility: N/A
9. Sensitive: air sensitive
10. CAS DataBase Reference: Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)(CAS DataBase Reference)
11. NIST Chemistry Reference: Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)(749935-02-2)
12. EPA Substance Registry System: Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)(749935-02-2)
Safety Data
1. Hazard Codes: N/A
2. Statements: N/A
3. Safety Statements: N/A
4. WGK Germany: 3
5. RTECS:
6. HazardClass: N/A
7. PackingGroup: N/A
8. Hazardous Substances Data: 749935-02-2(Hazardous Substances Data)

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749935-02-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 749935-02-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 7,4,9,9,3 and 5 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 749935-02:
(8*7)+(7*4)+(6*9)+(5*9)+(4*3)+(3*5)+(2*0)+(1*2)=212
212 % 10 = 2
So 749935-02-2 is a valid CAS Registry Number.

749935-02-2 Well-known Company Product Price

Brand
(Code)Product description
CAS number
Packaging
Price
Detail

TCI America
(N1017) [NH₂Me₂][(RuCl((R)-tolbinap))₂(μ-Cl)₃]
749935-02-2
200mg
450.00CNY
Detail

TCI America
(N1017) [NH₂Me₂][(RuCl((R)-tolbinap))₂(μ-Cl)₃]
749935-02-2
1g
1,570.00CNY
Detail

Aldrich
(692441) (R)-[(RuCl(T-BINAP))₂(μ-Cl)₃[NH₂Me₂]
749935-02-2
692441-100MG
272.61CNY
Detail

Aldrich
(692441) (R)-[(RuCl(T-BINAP))₂(μ-Cl)₃[NH₂Me₂]
749935-02-2
692441-500MG
1,049.49CNY
Detail

749935-02-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name	[NH2Me2][(RuCl((R)-tolbinap))2(μ-Cl)3]

1.2 Other means of identification

Product number	-
Other names	Dimethylammonium Dichlorotri(μ-chloro)bis[()-(+)-2,2'-bis(di--tolylphosphino)-1,1'-binaphthyl]diruthenate(II)

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:749935-02-2 SDS

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