75031-47-9Relevant academic research and scientific papers
Ene reaction of arynes with alkynes
Jayanth, Thiruvellore Thatai,Jeganmohan, Masilamani,Cheng, Mu-Jeng,Chu, San-Van,Cheng, Chien-Hong
, p. 2232 - 2233 (2007/10/03)
Arynes, generated in situ from ortho-silylaryl triflates, undergo ene reaction with alkynes possessing propargylic hydrogen in the presence of KF/18-crown-6 in THF at room temperature to give substituted phenylallenes. Various terminal and internal alkyne
Organocuprate-Induded Coupling of Propargyl or Enyne Alcohols Using (Methylphenylamino)tributylphosphonium Iodide. Regiocontrolled Synthesis of Allenes and Conjugated Enynes
Tanigawa, Yoshio,Murahashi, Shun-Ichi
, p. 4536 - 4538 (2007/10/02)
Regioselective synthesis of allenes is directly achieved via organocuprate-mediated γ-coupling of propargyl alcohols by using the title reagent (1). Alternatively, the coupling between 1,4-enyn-3-ols and alkyllithium affords the conjugated Z enynes regio-
