750586-53-9Relevant academic research and scientific papers
2-Aminothiabutadiene as useful building block in the synthesis of 2-aminothiopyrans and 2-aminothiophenes
Robin, Aelig,Meslin, Jean-Claude,Deniaud, David
, p. 1633 - 1640 (2004)
We report a reliable and regiocontrolled alternative route to unsubstituted 2-aminothiopyrans and 2-aminothiophenes. These sulfur heterocycles were prepared by reaction of protected aminothiabutadiene 1 with acrylic dienophiles or acceptor-substituted halomethyl compounds. All compounds were fully characterized by IR, HRMS, and 13C and 1H NMR spectroscopy.
