750596-75-9Relevant academic research and scientific papers
Highly diastereo- and enantioselective reactions of enecarbamates with ethyl glyoxylate to give optically active syn and anti α-alkyl-β- hydroxy imines and ketones
Matsubara, Ryosuke,Nakamura, Yoshitaka,Kobayashi, Shu
, p. 3258 - 3260 (2007/10/03)
The remarkably selective addition of enecarbamates 2 to ethyl glyoxylate (1) in the presence of a copper-dilmine catalyst (0.1 mol%) gives the corresponding imines 3 in high yields with excellent enantioselectivities. A concerted aza-enetype reaction mech
Highly diastereo- and enantioselective reactions of enecarbamates with an aldehyde
Matsubara, Ryosuke,Vital, Paulo,Nakamura, Yoshitaka,Kiyohara, Hiroshi,Kobayashi, Shu
, p. 9769 - 9784 (2007/10/03)
Catalytic asymmetric addition reactions of enecarbamates with ethyl glyoxylate have been developed using CuClO4·4CH3CN and a diimine ligand as the catalyst. Highly diastereo- and enantioselective addition reactions of α-mono-substitu
