750646-77-6

Basic information

• Product Name: 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methylbenzoyl)-5-phenyldipyrromethane
• Synonyms: 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methylbenzoyl)-5-phenyldipyrromethane
• CAS NO: 750646-77-6
• Molecular Weight: 460.427
• Mol File: 750646-77-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methylbenzoyl)-5-phenyldipyrromethane(CAS DataBase Reference)
• NIST Chemistry Reference: 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methylbenzoyl)-5-phenyldipyrromethane(750646-77-6)
• EPA Substance Registry System: 10-(9-borabicyclo[3.3.1]non-9-yl)-1-(4-methylbenzoyl)-5-phenyldipyrromethane(750646-77-6)

Safety Data

• Hazardous Substances Data: 750646-77-6(Hazardous Substances Data)

Upstream product

• 62731-43-5 9-BBN triflate 
• 171523-03-8 1-(p-methylbenzoyl)-5-phenyldipyrromethane 
• 121-44-8 triethylamine 

Downstream Products

• 871822-78-5 10-(9-borabicyclo[3.3.1]non-yl)-1-bromo-5-phenyl-9-p-toluoyldipyrromethane 
• 171523-03-8 1-(p-methylbenzoyl)-5-phenyldipyrromethane 
• 132313-39-4 5,15-bis-(4-methylphenyl)-10,20-diphenyl-porphyrin 

Relevant articles and documents

Metal complexation of 1-acyldipyrromethanes and porphyrins formed therefrom

A first aspect of the invention is a method of making a porphyrin-metal complex, comprising: (a) providing a first reagent selected from the group consisting of 1-acyldipyrromethanes, 1-acyldipyrrins, dipyrromethane-1-carbinols 1,9-diacyldipyrromethanes and 1,9-diacyldipyrrins; and then (b) condensing the first reagent with either itself (in the case of 1-acyldipyrromethanes, 1-acyldipyrrins, and dipyrromethane-1-carbinols) or a dipyrromethane (in the case of 1,9-diacyldipyrromethanes and 1,9-diacyldipyrrins) in a reaction mixture comprising a solvent and a second reagent selected from the group consisting of palladium and copper complexes to produce the porphyrin-metal complex (with the metal being palladium or copper). In preferred embodiments of the foregoing, the reaction mixture further comprises a base such as KOH or NaH.