7507-68-8

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

InChI:InChI=1/C12H20O3/c1-5-15-10(14)12(4)8-6-7-11(2,3)9(12)13/h5-8H2,1-4H3/t12-/m1/s1

Upstream product

• 74-83-9 methyl bromide 
• 55233-98-2 ethyl 2-oxo-3,3-dimethyl-cyclohexanecarboxylate 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 
• 74-88-4 methyl iodide 

Downstream Products

• 13487-68-8 2-Hydroxy-1,2,3,3-tetramethyl-cyclohexanecarboxylic acid 
• 1008357-55-8 1,3,3-trimethyl-2-oxocyclohexanecarboxylic acid benzyl ester 
• 74510-32-0 2,6,6-Trimethyl-6-<(4-methylphenylsulfonyloxy)methyl>cyclohexanon 
• 74510-31-9 2,6,6-Trimethyl-6-<(4-methylphenylsulfonyloxy)methyl>cyclohexanol 
• 74510-33-1 2-(Methoxymethyl)-2,6,6-trimethylcyclohexanon 
• 2408-37-9 2,2,6-trimethylcyclohexan-1-one 
• 74523-53-8 2-(Hydroxymethyl)-2,6,6-trimethylcyclohexanol 

Relevant academic research and scientific papers

Synthesis of five-and six-membered 1,3,3-trimethyl-2-(trimethylsilyl) cycloalkenes: A novel preparation of alkyl/alkenyl/aryl 2,5,5-trimethyl-1- cyclopentenyl ketones

1,3,3-trimethyl-2-(trimethylsilyl)cyclopentene and 1,3,3-trimethyl-2- -(trimethylsilyl)cyclohexene were prepared in good yields by the Wurtz-Fittig coupling reaction of the corresponding 2-iodo-1,3,3-trimethylcyclopentene and 2-chloro-1,3,3-trimethylcyclohexene with metallic sodium and chlorotrimethylsilane in anhydrous ether solvent. The Friedel-Crafts acylation reaction of 1,3,3-trimethyl-2-(trimethylsilyl)cyclopentene with six different acid chlorides and the novel preparation of six alkyl/alkenyl/aryl 2,5,5-trimethyl-1-cyclopentenyl ketones are reported.

Cabinet for locking a distributor and method

A device for dispensing items comprises a cabinet having an interior for storing items. A dispenser frame is coupled to the cabinet and is configured to be accessed, such as by pulling the dispenser frame from the cabinet. The dispenser frame includes a plurality of dividers that are configured to hold the plurality of dispensing mechanisms that each hold multiple items within the storage area. Further, the dividers are reconfigurable to permit the arrangement of the dispensing mechanisms to be adjusted. A lockable door is coupled to the front of the cabinet in front of the dispenser frame. The door may be opened to provide access to the interior of the cabinet and to the dispenser frame. A dispense drawer is positioned below the storage area so that items dispensed from the dispensing mechanisms.

Total synthesis of (±)-dihydroactinidiolide using selenium-stabilized carbenium ion

A new, short total synthesis of dihydroactinidiolide 1 is described using selenium carbenium ion-promoted carbon-carbon bond formation as the key step. Our synthetic strategy starts with a lactonization reaction between 1,3,3-trimethylcyclohexene 13 and α-chloro-α-phenylseleno ethyl acetate 14, affording the key intermediate, α-phenylseleno-γ-butyro lactone 15, which reacted via a selenoxide elimination to the target compound 1.