7507-86-0

Basic information

• Product Name: 2-Bromo-5-methoxybenzaldehyde
• Synonyms: 2-BROMO-5-METHOXYBENZALDEHYDE;AKOS B004279;2-BROMO-4-METHOXYBENZALDEHYDE;3-Methoxy-6-bromobenzaldehyde;4-Bromo-3-formylanisole;4-Bromo-3-formylanisole, 6-Bromo-m-anisaldehyde;2-Bromo-5-methoxybenzaldehyde 97%;EOS-60499
• CAS NO: 7507-86-0
• Molecular Formula: C₈H₇BrO₂
• Molecular Weight: 215.04
• Product Categories: Aromatic Aldehydes & Derivatives (substituted);Benzaldehyde;Aryl;Halogenated;Organohalides;Adehydes, Acetals & Ketones;Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds;aldehyde| alkyl bromide
• Mol File: 7507-86-0.mol
• Article Data: 68

Chemical Properties

• Melting Point: 71-76 ºC
• Boiling Point: 284.3 °C at 760 mmHg
• Flash Point: 125.7 °C
• Appearance: /
• Density: 1.522 g/cm³
• Vapor Pressure: 0.003mmHg at 25°C
• Refractive Index: 1.585
• Storage Temp.: Room temperature.
• Solubility: Acetonitrile (Slightly), Chloroform (Slightly)
• CAS DataBase Reference: 2-Bromo-5-methoxybenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromo-5-methoxybenzaldehyde(7507-86-0)
• EPA Substance Registry System: 2-Bromo-5-methoxybenzaldehyde(7507-86-0)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 36/37/38-22
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 7507-86-0(Hazardous Substances Data)

Usage

Chemical Properties

White powder

Uses

2-Bromo-5-methoxybenzaldehyde is used in preparation of Benzimidazole Quinolines. Also, used in preparation of Cyclopentenes, Polycycles, Benzocarbocycles/N-Heterocycle derivatives.

InChI:InChI=1/C8H7BrO2/c1-11-7-3-2-6(5-10)8(9)4-7/h2-5H,1H3

Upstream product

• 2973-80-0 2-bromo-5-hydroxybenzaldehyde 
• 74-88-4 methyl iodide 
• 591-31-1 3-methoxy-benzaldehyde 
• 1171119-65-5 5-(2-bromo-5-methoxybenzylidene)-2,2-dimethyl-1,3-dioxane-4,6-dion 
• 150192-39-5 2-Bromo-5-methoxybenzyl alcohol 
• 26831-52-7 2-amino-5-methoxybenzaldehyde 
• 20357-24-8 5-methoxy-2-nitro-benzaldehyde 
• 100-83-4 meta-hydroxybenzaldehyde 
• 19614-12-1 2-bromo-5-methoxybenzyl bromide 
• 27060-75-9 4-bromo-3-methylanisole 
• 22921-68-2 2-bromo-5-methoxy-benzoic acid 
• 681427-75-8 1-bromo-2-dibromomethyl-4-methoxybenzene 
• 77-78-1 dimethyl sulfate 
• 6971-51-3 3-methoxybenzyl alcohol 

Downstream Products

• 70603-19-9 6-methoxy-2,3-diphenyl-1H-inden-1-one 
• 71095-25-5 1-(2-Brom-5-methoxyphenyl)-propanol 
• 71095-23-3 1-(2′-bromo-5′-methoxyphenyl)ethan-1-ol 
• 205883-93-8 3-(2-formyl-4-methoxyphenyl)-2-propenoic acid 1,1-dimethylethyl ester 
• 524938-12-3 5-methoxy-2-[2-phenylsulfonyl-2-(trimethylsilyl)ethyl]benzaldehyde 
• 205677-05-0 N-(2-bromo-5-methoxybenzyl)-2,2,2-trifluoroethylamine 
• 558483-93-5 N-(2-bromo-5-methoxybenzyl)butylamine 
• 2811-50-9 7-methoxy-4-vinyl-1,2-dihydronaphthalene 
• 95280-64-1 (+/-)-(3aR,3bS,11aS)-7-methoxy-3a,3b,4,5,11,11a-hexahydrophenanthro[1,2-c]furan-1,3-dione 
• 681427-55-4 2-(but-3-enyl)-1-ethynyl4-methoxybenzene 
• 681427-54-3 1-(5-methoxy-2-((trimethylsilyl)ethynyl)phenyl)but-3-en-1-ol 
• 286859-57-2 2-(2-(2-epoxyethyl)-4-methoxyphenyl)benzo[b]thiophene 
• 220429-89-0 C₄₃H₃₄Br₂O₄ 
• 220429-88-9 (E)-1-[[4-(2-benzyloxy-5-dimethylphosphonomethyl)phenoxy]phenyl]-2-[2-bromo-5-methoxyphenyl]ethene 

Relevant articles and documents

Elaboration of the isochromane system of stephaoxocanes employing an Oxa-Pictet Spengler type cyclization

An approach to the synthesis of the isochromane moiety embodying the AC-ring system of the stephaoxocanes, by the use of an Oxa-Pictet Spengler type cyclization strategy, is reported.

Catalytic Cyclotrimerization Pathway for Synthesis of Selaginpulvilins C and D: Scope and Limitations

A facile and unified approach to the main selaginpulvilin's framework was achieved by catalytic [2 + 2 + 2]-cyclotrimerization of a triyne with monosubtituted alkynes. The reaction proceeded with high "ortho"selectivity by using Wilkinson's catalyst (RhCl

A novel donor-π-acceptor anthracene monomer: Towards faster and milder reversible dimerization

A novel functional 2,6-substituted donor-acceptor anthracene derivative, bearing a long alkyl spacer and a polymerizable end-group, is synthesized from readily available compounds. This monomer possesses conjugated electron donor and acceptor moieties to achieve UV absorption and anthracene dimerization at higher wavelengths and under milder conditions, than anthracene and other reported anthracene derivatives. The compound was shown to absorb at higher wavelengths and dimerize much faster compared to most 9-substituted anthracenes. The fast photochemical and relatively slow thermal scission of the dimers were studied and related to the chemical structure, i.e. the 2,6-substitution.