75072-59-2

Upstream product

• 61157-31-1 3-phenylpropionyltrimethylsilane 
• 693-02-7 hex-1-yne 
• 32359-01-6 hexenylmagnesium bromide 

Downstream Products

• 75072-67-2 (E)-5-Methyl-1-phenyl-non-4-en-3-one 
• 73341-04-5 5-methyl-1-phenyl-3-((trimethylsilyl)oxy)-3,4-nonadiene 
• 75072-75-2 C₁₈H₂₇LiOSi 
• 75085-61-9 Trimethyl-(1-phenethyl-hepta-1,2-dienyloxy)-silane 
• 1240781-29-6 C₁₈H₂₈OSi 

Relevant academic research and scientific papers

Stereoselective syntheses of trisubstituted olefins via platinum catalysis: α-Silylenones with geometrical complementarity

The stereoselective syntheses of α-silylenones using catalytic PtCl2 are reported. Via alkyne activation, α- hydroxypropargylsilanes are converted to (Z)-silylenones through a highly selective silicon migration. The complementary (E)-silylenone

SPECIFIC GENERATION OF LITHIATED 3-TRIMETHYLSILOXY-1,2-PROPADIENE DERIVATIVES FROM 1-(TRIMETHYLSILYL)PROPARGYL ALCOHOLS.

1-(Trimethylsilyl)propargyl alcohols have been prepared by treating acyltrimethylsilanes with magnesium acetylides, and their base-induced reactions involving rearrangement of silyl group have been examined. Treatment of the alcohol with an equimolar amou

BASE-INDUCED REARRANGEMENT OF 1-TRIMETHYLSILYLPROPARGYL ALCOHOL. GENERATION OF LITHIATED TRIMETHYLSILOXYALLENES AND THEIR REACTIONS

Under the effect of butyllithium, 1-trimethylsilylpropagyl alcohol undergoes rearrangement to afford the corresponding trimethylsiloxyallene or its lithiated one, which can be used for the preparation of α,β-unsaturated ketone derivatives.