75072-60-5Relevant articles and documents
SPECIFIC GENERATION OF LITHIATED 3-TRIMETHYLSILOXY-1,2-PROPADIENE DERIVATIVES FROM 1-(TRIMETHYLSILYL)PROPARGYL ALCOHOLS.
Kato,Kuwajima
, p. 827 - 830 (2007/10/02)
1-(Trimethylsilyl)propargyl alcohols have been prepared by treating acyltrimethylsilanes with magnesium acetylides, and their base-induced reactions involving rearrangement of silyl group have been examined. Treatment of the alcohol with an equimolar amou
BASE-INDUCED REARRANGEMENT OF 1-TRIMETHYLSILYLPROPARGYL ALCOHOL. GENERATION OF LITHIATED TRIMETHYLSILOXYALLENES AND THEIR REACTIONS
Kuwajima, Isao,Kato, Masahiro
, p. 623 - 626 (2007/10/02)
Under the effect of butyllithium, 1-trimethylsilylpropagyl alcohol undergoes rearrangement to afford the corresponding trimethylsiloxyallene or its lithiated one, which can be used for the preparation of α,β-unsaturated ketone derivatives.