75079-84-4Relevant academic research and scientific papers
Reaction of propargyl bromides with silver and sodium nitrites. A new method for the synthesis of nitroisoxazoles
Mechkov, Ts. D.,Sulimov, I. G.,Usik, N. V.,Mladenov, I.,Perekalin, V. V.
, p. 1148 - 1150 (2007/10/02)
The reaction of primary and secondary propargyl bromides with silver and sodium nitrites was investigated for the first time.In contrast to alkyl and allyl halides, the reaction does not stop at the stage of the formation of the normal mononitro compounds for the Meyer - Kornblum reaction and results in the synthesis of derivatives of 3- or 4-nitroisoxazoles.
