75081-92-4

Usage

InChI:InChI=1/C23H29NO12/c1-8(22(32)24-13-14(27)16(29)21-20(15(13)28)33-7-34-21)5-10-3-4-12(11(26)6-10)35-23-18(31)17(30)19(36-23)9(2)25/h3-6,13-21,23,26-31H,7H2,1-2H3,(H,24,32)/b8-5+/t13-,14+,15-,16-,17+,18+,19+,20+,21-,23-/m1/s1

Upstream product

• 1410798-42-3 (-)-(2E)-3-(4-{[6-deoxy-2,3-bis-O-(triisopropylsilyl)-β-D-arabino-hexofuranosyl-5-ulose]oxy}-3-hydroxphenyl)-2-methyl-N-[(3aS,4R,5R,6S,7R,7aR)-4,6,7-trihydroxyhexahydro-1,3-benzodioxol-5-yl] acrylamide 
• 1410798-30-9 2,2,7-trimethyl-3a,4,5,5a,8a,8b-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[2,1-d]oxazole-4,5-diol 
• 1410798-31-0 2,2,8-trimethyl-3a,3b,6a,6b,9a,9b-hexahydro-1,3,4,6,7-pentaoxa-9-aza-trindene 
• 60505-07-9 2,2,8-trimethyl-3a,3b,6a,6b,9a,9b-hexahydro-1,3,4,6,7-pentaoxa-9-aza-trindene 
• 1410798-41-2 (-)-(2E)-3-[4-{[6-deoxy-2,3-bis-O-(triisopropylsilyl)-β-D-arabino-hexofuranosyl-5-ulose]oxy}-3-hydroxy-phenyl]-2-methylacrylic acid 
• 1190266-98-8 (E)-methyl 3-(3-(allyloxy)-4-hydroxyphenyl)-2-methylacrylate 
• 139-85-5 3,4-dihydroxybenzaldehyde 
• 79822-65-4 3-hydroxy-4-(2-propenyloxy)benzaldehyde 
• 261631-95-2 (-)-(1S)-1-{(4S,5S)-5-[(1S)-1-hydroxy-2-propenyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-2-propen-1-ol 
• 277744-82-8 (3S,4S,5S,6S)-3,6-dihydroxy-4,5-(isopropylidenedioxy)-cyclohexene 
• 1188303-61-8 (1S,4S,5S,6S)-4-azido-5,6-(isopropylidenedioxy)cyclohex-2-enol 
• 1410798-25-2 N-((3aS,4S,7S,7aS)-7-hydroxy-2,2-dimethyl-3a,4,7,7a-tetrahydrobenzo[d][1,3]dioxol-4-yl)acetamide 
• 1410798-26-3 2,2,7-trimethyl-3a,5a,8a,8b-tetrahydro-[1,3]dioxolo[4',5':3,4]benzo[2,1-d]oxazol 
• 66537-92-6 methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside 

Downstream Products

• 66740-54-3 Hygromycin-hexaacetat 

Relevant academic research and scientific papers

Chiral pool based efficient synthesis of the aminocyclitol core and furanoside of (-)- hygromycin A: Formal total synthesis of (-)-hygromycin A

A chiral pool based synthetic strategy that leads from the readily available and inexpensive C2-symmetric tartaric acids to the chiral O-isopropylidenebenzooxazolei- a convenient precursor to the aminocyclitol core of hygromycin A as well as the chiral γ-disilyloxybutyrolactone-a pivotal intermediate to approach to the furanoside of hygromycin A.

Total Synthesis of Antibiotic Hygromycin A

The first total synthesis of the antibiotic (-)-hygromycin A (1) has been achieved by a coupling reaction of the sugar moiety (2) and the cyclitol moiety (3).Both components were synthesized in homochiral forms starting from D-glucose.This synthesis fully

Total Synthesis of Hygromycin A

The first complete synthesis of antibiotic hygromycin A is reported; coupling of the protected sugar moiety (2) and the aminocyclitol (3) derived from D-glucose as the optically active form, followed by deprotection, gives the product (1) which was identi