7510-29-4

Usage

Uses

Used in Solvent Applications:
2,4,6-tributyl-1,3,5-trioxane is used as a solvent due to its ability to dissolve a wide range of substances, making it suitable for various industrial processes.
Used in Perfume and Fragrance Manufacturing:
2,4,6-tributyl-1,3,5-trioxane is used as a component in the production of perfumes and other fragrance products, contributing to their stability and longevity.
Used in Plastics Industry:
2,4,6-tributyl-1,3,5-trioxane is used as a stabilizer in plastics, enhancing their durability and resistance to degradation.
Used in Chemical Production:
2,4,6-tributyl-1,3,5-trioxane serves as a chemical intermediate, playing a crucial role in the synthesis of other chemicals.

Upstream product

• 110-62-3 pentanal 

Relevant academic research and scientific papers

A convenient approach for the synthesis of 1,3,5-trioxanes under solvent-free conditions at room temperature

A series of environmentally benign bis-SO3H-functionalized Bronsted acidic ionic liquids were synthesized by using aliphatic polyamines and 1,3-propanesultone as the source chemicals. These ionic liquids acted as efficient inexpensive and recyclable catalysts for cyclotrimerization of aliphatic aldehydes at room temperature under solvent-free conditions. The reactions proceeded smoothly with good to excellent isolated yields (66.9-97.6 %=) and were generally complete in 1.5 h when the amount of ionic liquids was 0.1 mol%. The ionic liquids could be recovered readily and reused five times without any significant loss in their catalytic activity. Graphical abstract: [Figure not available: see fulltext.]

Novel acidic ionic liquids as efficient and recyclable catalysts for the cyclotrimerization of aldehydes

A mild, efficient, and ecofriendly procedure for cyclotrimerization of aldehydes was realized by using a series of novel Brnsted acidic ionic liquids (BAILs) consisting of double-SO3H groups in cations as catalysts. Good conversion of aldehydes and selectivity of trialkyl-1,3,5-trioxanes were achieved by using 1mol% of BAILs. In addition, the catalyst system could be recycled and reused at least eight times without apparent loss of activity. Taylor & Francis Group, LLC.

Tandem reactions of Friedel-Crafts/aldehyde cyclotrimerization catalyzed by an organotungsten Lewis acid

The tris(2-pyridyl)phosphine complex [P(2-py)3 W(CO)(NO)2](BF4)2 acts as a Lewis acid catalyst precursor for the tandem reactions of Friedel-Crafts/aldehyde cyclotrimerization, which lead to the formation of a series of hyper-branched star polymers.

Efficient oxidative cleavage of olefins to carboxylic acids with hydrogen peroxide catalyzed by methyltrioctylammonium tetrakis(oxodiperoxotungsto)phosphate(3-) under two-phase conditions. Synthetic aspects and investigation of the reaction course

The oxidative cleavage of alkenes to carboxylic acids with 40% w/v aqueous hydrogen peroxide catalyzed by methyltrioctylammonium tetrakis(oxodiperoxotungsto)phosphate(3-) (1a) is reported to occur in high yields and selectivities under two-phase conditions in the absence of organic solvents. On the basis of a study of the reaction, two main reaction pathways leading to acids have been recognized, the first one involving the perhydrolysis and the second one the hydrolysis of the epoxide initially formed. The "perhydrolytic" reaction pathway appears to play a primary role in the oxidation of medium- and long-chain alkenes to acids, while it intervenes to a rather limited extent in the oxidation of arylalkenes and C5-C7 cycloalkenes. The occurrence of this pathway has been proved by the isolation of the intermediate β-hydroperoxy alcohols and their transformation into acids with H2O2 and la. The course of this transformation, involving an initial oxidation (to α-oxo hydroperoxide) or decomposition (to carbonyl compounds) of the β-hydroperoxy alcohol intermediate, is described. The primary oxidation products, α-hydroperoxy ketones, have been isolated in the case of internal β-hydroperoxy alcohols, whereas their presence has been evidenced with terminal β-hydroperoxy alcohols bearing a secondary hydroxy group. Hydrogen peroxide concentration appears to exert a remarkable influence on medium acidity, and its effects on the reaction efficiency are shown.

Process for the manufacture of cyclic acetals of aliphatic aldehydes

A process for preparing a cyclic acetal from a saturated, aliphatic aldehyde comprises contacting a saturated, aliphatic aldehyde of 2-16 carbon atoms with a silica gel.