75102-56-6Relevant academic research and scientific papers
THE MARKOVNIKOV-ANTIMARKOVNIKOV ADDITION OF m-THIOCRESOL AND p-NITROTHIOPHENOL TO INDENE
Baeza, Jaime,Freer, Juanita,Palma, Graciela,Szmant, Harry H.
, p. 213 - 218 (2007/10/02)
The addition of m-thiocresol and p-nitrothiophenol to indene has been studied under a variety of acidic conditions.The reaction of indene and m-thiocresol gave both Markovnikov and anti-Markovnikov adducts, in 58percent and 42percent yields, respectively.
Determination of the Stereochemistry in the Addition of Thiols to Indene
Szmant, H. Harry,Baeza H, Jaime
, p. 4902 - 4906 (2007/10/02)
A methodology for the determination of the stereoselectivity in the addition of thiols to indene is described.The chemical method employs an S-deutero thiol, the thermal elimination reaction of the sulfoxides derived from the adducts, and the determinatio
