75107-99-2Relevant academic research and scientific papers
Fluorination with Complex Metal Fluorides. Part 5. Fluorination of Nitriles over Caesium Tetrafluorocobaltate(III)
Phull, Gurjeet S.,Plevey, Raymond G.,Rendell, Richard W.,Tatlow, John Colin
, p. 1507 - 1511 (2007/10/02)
Benzonitrile and the isomers of benzenedicarbonitrile (phthalo-, isophthalo-, and terephthalo-nitrile) have been fluorinated over caesium tetrafluorocobaltate(III) at elevated temperatures to give a mixtures containing undecafluorocyclohexanecarbonitrile.In addition the dinitriles gave decreasing yields (1,4- > 1,3- > 1,2-) of the corresponding cyclohexanedircarbonitriles.Some reactions (addition, defluorination, hydrolysis, and reduction) of undecafluorocyclohexanecarbonitrile are described.
