75108-07-5Relevant academic research and scientific papers
PREPARATION ET ESSAIS DE DEDOUBLEMENT ENZYMATIQUE D'ACETOXYMETHYL-ET HYDROXYMETHYLSILANES CHIRAUX
Aouf, N. E.,Djerourou, A. H.,Blanco, L.
, p. 207 - 216 (2007/10/02)
Various chirals acetoxymethyl- and hydroxymethylsilanes were synthesized from commercially available chlorosilanes.Several enzymatic-catalyzed hydrolyses or transesterifications have been attempted on these products.Key words: Esterases; lipases; silicium
Syntheses of New Optically Active Organosilanes and Their Applications for the Optical-Purity-Determining Agents
Terunuma, Daiyo,Kato, Masato,Kamei, Masanao,Uchida, Hidekatsuu,Ueno, Satoshi,Nohira, Hiroyuki
, p. 3581 - 3588 (2007/10/02)
New optically active organosilicon compounds such as (benzylmethylphenylsilyl)acetic acid (1) and (ethylmethylphenylsilyl)acetic acid (2) were synthesized.Application of these acids as the optical purity determining agents for chiral amines and alcohols were successfully carried out.In addition, it was also revealed that optically active (benzylmethylphenylsilyl)methylamine (3) and methylamine (4) are able to be used as the optical purity determining agents for chiral carboxylic acids.
Optical Resolutions and Configurations of Benzylmethylphenylsilylmethylamine and Its Derivatives
Terunuma, Daiyo,Murakami, Katsutoshi,Kokubo, Masanori,Senda, Kazuhisa,Nohira, Hiroyuki
, p. 789 - 794 (2007/10/02)
New optically active α-amino organosilanes, such as benzylmethylphenylsilylmethylamine, benzylmethyltolylsilylmethylamines, and anisylbenzylmethylsilylmethylamines, were obtained by the fractional crystallization of the salts of the amines and (+)-tartari
