Cas 75120-60-4,N(C4H9)4(1+)*Mn(C4H2NCC6H5)4(C3H3N2)2(1-) = (N(C4H9)4)[Mn(C4H2NCC6H5)4(C3H3N2)2]

75120-60-4

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Product Name: N(C₄H₉)4⁽¹⁺⁾*Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2^(1-) = (N(C₄H₉)4)[Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2]
Synonyms:
CAS NO:75120-60-4
Molecular Formula:
Molecular Weight: 1044.28
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: N(C₄H₉)4⁽¹⁺⁾*Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2^(1-) = (N(C₄H₉)4)[Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2](CAS DataBase Reference)
NIST Chemistry Reference: N(C₄H₉)4⁽¹⁺⁾*Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2^(1-) = (N(C₄H₉)4)[Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2](75120-60-4)
EPA Substance Registry System: N(C₄H₉)4⁽¹⁺⁾*Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2^(1-) = (N(C₄H₉)4)[Mn(C₄H₂NCC₆H₅)4(C₃H₃N₂)2](75120-60-4)

Safety Data

Hazard Codes: N/A
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Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 75120-60-4(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 75120-60-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,5,1,2 and 0 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 75120-60:
(7*7)+(6*5)+(5*1)+(4*2)+(3*0)+(2*6)+(1*0)=104
104 % 10 = 4
So 75120-60-4 is a valid CAS Registry Number.

75120-60-4Upstream product

67035-78-3 tetra-n-butylammonium imidazolate

75120-60-4Downstream Products

75120-60-4Relevant academic research and scientific papers

Imidazole Complexes of Iron and Manganese Tetraphenylporphyrins

Landrum, John T.,Hatano, K.,Scheidt, W. Robert,Reed, Christopher A.

, p. 6729 - 6735 (2007/10/02)

The possible importance of partially or completely deprotonated imidazole ligation in the hemoproteins has led us to investigate imidazolate, Im-, complexes of iron(II,III) and manganese(II,III) meso-tetraphenylporphyrin (TPP).Tetrabutylammonium imidazolate is a convenient reagent for the synthesis of isolable complexes.By steric and stoichiometric control the stereochemistry can be manipulated to give complexes with most possible coordination numbers and spin states. - is the first example of a low-spin Mn(III) porphyrin complex and demonstrates the greater ligand field strength of imidazolate over imidazole.The X-ray crystal structure of the polymer n is reported.It shiws layers of parallel chains with alternate layers having their quasi-linear chains approximately orthogonal to each other.There is a short-short/long-long alternation of Mn-N(Im) bond lengths (2.186 (5) and 2.280 (4) Angstroem) interpreted as reflecting alternating predominantly low- and high-spin Mn(III) atoms along the polymeric chain.The average Mn-N(porph) bond distance is 2.019 (4) Angstroem.Crystal data: a = 20.073 (3) Angstroem, b = 16.885 (3) Angstroem, c = 22.590 (5) Angstroem, β = 104.36 (2) deg, space group C2/c, Z = 8 (Mn(Im)(TPP) units).

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