75136-53-7

Upstream product

• 75-31-0 isopropylamine 
• 134-81-6 benzil 

Downstream Products

• 101859-63-6 (CH₃)5Al₂(CH₃)2CHNC(C₆H₅)C(C₆H₅)(CH₃)O 
• 101859-61-4 (Al(CH₃)3)2[CH(CH₃)2NC(C₆H₅)C(C₆H₅)O] 
• 149006-14-4 Ru(CO)2(P(C₆H₅)3)(OC(C₆H₅)C(C₆H₅)NCH(CH₃)2) 
• 102305-33-9 {((CH₃CH₂)3P)PtCl₂N(CH(CH₃)2)C(C₆H₅)COC₆H₅} 
• 86048-48-8 3-isopropyl-4,5-diphenyl-4-oxazoline-2-thione 
• 86048-47-7 3-isopropyl-4,5-diphenyl-4-oxazolin-2-one 
• 83165-63-3 1-isopropyl-3,3,4-triphenyl-4-(α-hydroxybenzyl)-azetidin-2-one 
• 83165-58-6 1-isopropyl-3,3,4-triphenyl-4-benzoyl-2-azetidinone 
• 3893-33-2 1,1',2,2'-tetraphenyl-2,2'-azinodiethanone 
• 913968-58-8 di-μ-chlorobis(2-[1-(isopropylimino-κN)-2-oxo-2-phenylethyl]phenyl-κC)dipalladium 
• 17685-52-8 triiron dodecarbonyl 

Relevant academic research and scientific papers

Titanium(IV) chloride induced reactions of ketones and C-acylimines with dimethylcyanamide

The reactions of ketones (benzophenone, 4-methylbenzophenone, acetophenone, acetone, and 2,2,4,4-tetramethyl-3-pentanone) and C-acylimines with dimethylcyanamide in the presence of titanium(IV) chloride were investigated. Benzophenone and 4-methylbenzophenone react with dimethylcyanamide to give 4,4-disubstituted 2-dimethylamino-3-aza-1-oxa-1,3-butadienes 5 and 4,4-disubstituted 2-dimethylanuno-1-N,N-dimethylcarbamoyl-1,3-diaza-1,3-butadienes 9. Ketones with enolizable hydrogen atoms undergo aldol reactions under these conditions. C-Acylimines 11b-11e, derived from benzil and substituted anilines, undergo [2 + 2] cycloaddition to dimethylcyanamide with subsequent ring opening to 1-(N,N-dimethylcarbamoyl)-2,3,4-triaryl-1,4-diaza-1,3-butadienes 15. 1,2-Diphenyl-2-(isopropylimino)ethanone (11a) reacts with dimethylcyanamide to give 2-dimethylamino-1-isopropyl-4,4-diphenyl-2-imidazolin-5-one (23) in a hitherto unknown multistep reaction. The structure of 23 was confirmed by an X-ray analysis. VCH Verlagsgesellschaft mbH, 1996.

Cyclization of Dianions from 2-Imino-1,2-diphenylethanone to Oxazolines, Oxazocines, and Oxazonines

The reaction of 2-imino-1,2-diphenylethanone with sodium in ether and subsequent addition of carbon disulfide or ethyl chloroformate resulted in the formation of 3,4,5-trisubstituted 4-oxazoline-2-thiones and 2-ones, respectively. 1,4-Oxazonines and 1,4-o

Syntheses of N-substituted 3,3,4-triphenyl-4-benzoylazetidin-2-ones and 3',3'-diphenyl spiro(acenaphthen-1-one-2,4'-azetidin-2'-ones); novel examples exhibiting a high reactivity of imino group in ketoimines

The reaction of 2-diazo-1,2-diphenylethanone (1) with 2-imino-1,2-diphenylethanones 2a-e gave new N-substituted 3,3,4-triphenyl-4-benzoylazetidin-2-ones 3a-e, together with 1,1',2,2'-tetraphenyl-2,2'-azinodiethanone (4).Similar reaction of 1 with 2-iminoa