75144-60-4Relevant articles and documents
Copper-Promoted Formation of Vinylsiloxanes
Bia?oń, Marietta,Dziuk, B?a?ej,Olijnyk, Volodymyr
, (2020)
The metathesis reactions of chlorovinylsilanes with copper(I) oxide are reported. The process is catalyzed by HCl which can be in situ generated via hydrolysis of chlorosilanes by traces of water present in the system. An appearance of olefin/CuCl π-intermediates can provide a stereoselectivity of the process and alter the pathway of siloxanes formation employing Cu2O as the source of oxygen. It was also shown that acetonitrile may be available as a solvent for construction of the systems with large preparative capabilities, including those based on the use atmospheric oxygen in siloxane synthesis.
Side products in the syntheses of vinylsilanes and vinylsiloxanes using vinylmagnesium chloride
Zhun
, p. 1746 - 1748 (2007/10/03)
Impurity of moisture in the solvent (tetrahydrofuran) alters the, normal scheme of formation of vinylmagnesiumm chloride and gives rise to several unexpected products: benzene, toluene, and methyl chloride. Side products forming in alkali hydrolysis of trivinylsilane and hydrochlorination of tetravinylsilane were isolated and identified.
REACTIVITY OF Si-H BONDS IN ORGANOSILANES
Zhun', V. I.,Zhun', A. B.,Vlasenko, S. D.,Belorusskaya, L. A.,Chernyshev, E. A.,Sheludyakov, V. D.
, p. 2266 - 2270 (2007/10/02)
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