75155-27-0Relevant academic research and scientific papers
A NOVEL METHOD FOR THE GEMINAL DIALKYLATION OF THE CARBONYL GROUP OF AROMATIC ALDEHYDES AND KETONES
Clarembeau, M.,Krief, A.
, p. 1719 - 1722 (2007/10/02)
The title transformation is efficiently achieved by using the selenium methodology which involves the sequential reductive alkylation of arylselenoacetals and of benzylselenides.
SYNTHESIS OF SELENOACETALS
Clarembeau, M.,Cravador, A.,Dumont, W.,Hevesi, L,Krief, A.,et al.
, p. 4793 - 4812 (2007/10/02)
This paper reports our results concerning the syntheses of various bis(alkylseleno)alkanes and some of their arylseleno analogues by different methods.The scope and limitation of each of them are presented.
Reduction vs. Acetalisation of some Carbonyl Compounds by means of Methylselenol and Lewis Acids
Cravador, Alfredo,Krief, Alain,Hevesi, Laszlo
, p. 451 (2007/10/02)
Aliphatic ketones and aromatic carbonyl compounds on reaction with methylselenol and a Lewis acid, are shown to undergo acetalisation and/or reduction to methyl selenide, the unexpected reduction reaction being predominant in most cases.
