75157-19-6Relevant academic research and scientific papers
New and improved methods for the conversion of nitroalkanes into geminal chloronitroso compounds
Bou-Moreno, Rafael,Luengo-Arratta, Sandra,Pons, Valerie,Motherwell, William B.
, p. 6 - 12 (2013)
The scope and limitations of a new method for the preparation of geminal chloronitroso compounds involving treatment of a nitronate anion with oxalyl chloride are described in full, and a milder, high yielding, and more chemoselective variant using the de
Six-Membered Cyclic Nitroso Acetals: Synthesis and Studies of the Nitrogen Inversion Process of N-Silyloxy-3,6-dihydro-2H-1,2-oxazines
Shved, Alexander S.,Tabolin, Andrey A.,Novikov, Roman A.,Nelyubina, Yulia V.,Timofeev, Vladimir P.,Ioffe, Sema L.
supporting information, p. 5569 - 5578 (2016/11/25)
Silyl nitronates undergo rhodium-catalyzed formal [3+3]-cycloaddition with enol diazoacetates to form N-silyloxy-3,6-dihydro-2H-1,2-oxazines. The scope of the reaction and the extent of the major side process were evaluated. A mechanistic scheme was propo
THE NEF REACTION ON TRIALKYLSILYL NITRONATES PROMOTED BY m-CHLOROPERBENZOIC ACID, AN EFFICIENT ROUTE TO α-ALKOXYKETONES FROM NITROALKANES
Aizpurus, J. M.,Oiarbide, M.,Palomo, C.
, p. 5361 - 5364 (2007/10/02)
Treatment of a nitroalkene with nucleophiles, followed by silylation of the resulting nitroalkane and subsequent treatment with m-chloroperbenzoic acid provides α-functionalized carbonyl compounds in good yields.
SYNTHESIS, PROPERTIES, AND CRYSTAL STRUCTURE OF SILYL NITRONATES (SILYL ESTERS OF ACI-NITROALKANES): TOWARDS THE SN2 REACTION PATH WITH RETENTION OF CONFIGURATION AT SILICON
Colvin, Ernest W.,Beck, Albert K.,Bastani, Bahram,Seebach, Dieter,Kai, Yasushi,Dunitz, Jack D.
, p. 697 - 710 (2007/10/02)
An efficient and flexible method for the preparation of silyl nitronates is described (see 1-10).NMR. spectral investigations indicate a rapid 1,3-silyl migration process, with an activation energy of about 10 kcal mol-1.X-ray crystallographic
