75197-06-7

Upstream product

• 30389-17-4 but-3-yn-2-amine 
• 624-64-6 trans-2-Butene 

Downstream Products

• 121731-61-1 (S)-N-(1-methyl-2-propen-1-yl) p-toluenesulfonamide 
• 878999-34-9 (1-(S)-methyl-allyl)carbamic acid benzyl ester 
• 108-27-0 5-methylpyrrolidin-2-one 
• 136649-76-8 2-Methyl-but-3-enoic acid (1-methyl-allyl)-amide 
• 136649-73-5 (E)-Pent-3-enoic acid (1-methyl-allyl)-amide 
• 136649-74-6 1,3-Bis-(1-methyl-allyl)-urea 
• 124218-91-3 1-benzyl-6-(α-methylallylamino)-3-(2',3',5'-tri-O-benzoyl-β-D-ribofuranosyl)uracil 
• 89192-84-7 N-(1-Methylallyl)-phenylmethanimine 
• 431-03-8 dimethylglyoxal 
• 78-93-3 butanone 
• 598-32-3 2-hydroxy-3-butene 
• 773148-94-0 5-chloro-6-(2,4,6-trifluorophenyl)-7-(1-methyl-2-propen-1-yl-)amino-[1,2,4]triazolo[1,5-a]pyrimidine 
• 267668-37-1 N-tert-butoxycarbonyl-N-(1-methyl-2-propenyl)amine 
• 133957-65-0 N-(but-3-en-2-yl)-benzamide 

Relevant academic research and scientific papers

The Reactions of Singlet NH Radicals with C4 Olefins in the Liquid Phase

The reactions of NH radicals with C4 olefins, trans- and cis-2-butenes, 1-butene, and isobutene, were investigated by the photolysis of hydrogen azide in the liquid olefin at 0 deg C and at the temperature of Dry Ice-methanol.Except for nitrogen and ammonia, amines and aziridines were found to be formed in good yield. 2-Butene-1-amine and trans-2,3-dimethylaziridine from trans-2-butene, 2-butene-1-amine and cis-2,3-dimethylaziridine from cis-2-butene, 3-butene-1- and 2-amines and 2-ethylaziridine from 1-butene, and 2-methyl-2-propene-1-amine and 2,2-dimethylaziridine from isobutene.These product formations were successfully explained by the insertion into the C-H bond and the addition to the double bond of olefin by the singlet NH radicals.In the case of 2-butene, no isomerized aziridine formation was observed.This result suggested that the triplet NH radicals rarely add to the double bond of olefin.