75197-97-6Relevant academic research and scientific papers
SELECTIVE REDUCTION OF β-FLUOROAZIDES TO β-FLUOROAMINES
Hamman, S.,Beguin, C.G.
, p. 191 - 196 (2007/10/02)
Three methods were tested to reduce chemoselectively β-fluoroazides into β-fluoroamines : catalytic hydrogenation, catalytic transfer hydrogenation, and reduction with triphenyl phosphine.The last was the best.
Preparation of Fluoro Amines by the Reaction of Aziridines with Hydrogen Fluoride in Pyridine Solution
Wade, Tamsir N.
, p. 5328 - 5333 (2007/10/02)
Hydrogen fluoride combines regiospecifically with aziridines (1) to give 2-fluoro amines (6) in good yields.Fluorine attack is in all cases completely directed to the most substituted ring carbon or to the benzylic carbon.The results, for benzylic aziridi
