75200-15-6Relevant academic research and scientific papers
REACTIONS OF HOMOBINUCLEAR PLATINUM AND PALLADIUM COMPLEXES WITH CARBON MONOXIDE
Dagnac, P.,Turpin, R.,Poilblanc, R.
, p. 123 - 130 (2007/10/02)
The reactivity of homobimetallic complexes of platinum(II) and palladium(II) containing diethyl(diphenylphosphinomethyl)amine (ddpa = (C6H5)2PCH2N(C2H5)2) as a bridging ligand has been investigated.Carbon monoxide reacts reversibly with these complexes.The species formed are binuclear carbonyl-bridged derivatives, which can isomerize to ionic terminal carbonyl complexes.Reaction of 22 with ddpa in dichloromethane gives the ionic platinum(I) complex 22, which reacts with carbon monoxide.Still, homobimetallic derivatives ofpalladium(I) are unstable, and none have been isolated.
