75207-34-0

Upstream product

• 92300-47-5 (+/-)-2-p-Tolyl-hepten-⁽²⁾-ol-⁽⁶⁾ 
• 10373-75-8 5-(p-Tolyl)-2-acetyl-hexansaeure-aethylester 
• 18402-90-9 (3E,5E)-3.5-heptadien-2-one 
• 5084-80-0 tri(4-tolyl)boroxine 
• 534-22-5 2-methylfuran 
• 70855-12-8 2-Methyl-5-<(4-methylphenyl)methyl>furan 
• 70855-13-9 1-(4-methylphenyl)-hexane-2,5-dione 
• 75207-29-3 6,6-(ethylenedithio)-3-hydroxy-2-p-tolylheptane 
• 104-81-4 4-Methylbenzyl bromide 
• 5838-08-4 1-(3-bromo-1-methyl-propyl)-4-methyl-benzene 
• 75207-30-6 Methanesulfonic acid 1-[2-(2-methyl-[1,3]dithiolan-2-yl)-ethyl]-2-p-tolyl-propyl ester 
• 75207-28-2 6,6-(ethylenedithio)-2-p-tolylheptan-3-one 
• 75207-27-1 5,5-(ethylenedithio)-1-p-tolylhexan-2-one 
• 75207-31-7 6,6-(ethylenedithio)-2-p-tolylhept-2-ene 

Downstream Products

• 92368-92-8 opt.-inakt. 2-p-Tolyl-heptanol-⁽⁶⁾ 
• 451-58-1 6-methyl-6-(4-tolyl)hept-1-ene 

Relevant academic research and scientific papers

Highly selective 1,6-addition of aryl boronic acids to α,β, γ,δ-unsaturated carbonyl compounds catalyzed by an indium complex

(Chemical Equation Presented) Perfect control: The catalytic 1,6-addition of aryl boronic acids to electron-deficient dienes was realized by use of an iridium catalyst (see scheme). High yields of the corresponding δ-arylated carbonyl compounds were obtai

A Simple and Efficient Total Synthesis of the Sesquiterpenes Cuparene and Iso-α-curcumene, from Furan Derivatives

3,3-Dimethyl-2-p-tolylcyclopentanone (7) was synthesised by 1,4-addition of lithium dimethylcuprate to 3-methyl-2-p-tolylcyclopentenone (6), which was derived from 5-methyl-2-(4-methylbenzyl)furan (4) through the diketone (5).Starting from the same intermediate (5), 2-p-tolylheptan-6-one (16) was also synthesised.These results constitute formal total syntheses of cuparene (9) and iso-α-curcumene (17) respectively.