7521-52-0Relevant articles and documents
GENERATION AND REACTIONS OF AZAXYLYLENES
Bowen, R. D.,Davies, D. E.,Fishwick, C. W. G.,Glasbey, T. O.,Noyce, S. J.,Storr, R. C.
, p. 4501 - 4504 (1982)
Azaxylenes produced by flash vacuum pyrolysis of 2-aminobenzylalcohols, dihydrobenzoxazinones and dihydrobenzoxazines undergo intramolecular cyclisation, H-shifts or Diels-Alder reactions, depending on their substituents.
CATALYSIS IN FLASH VACUUM PYROLYSIS
Hodgetts, I.,Noyce, S. J.,Storr, R. C.
, p. 5435 - 5438 (2007/10/02)
The temperature required for flash pyrolytic elimination of water from o-aminobenzyl alcohols and of carbon dioxide from dihydrobenzoxazinones to give azaxylylenes is considerably lowered by the presence of alumina and silica gel in the hot zone.