75232-85-8Relevant academic research and scientific papers
(Trimethylsilyl)vinylketene: A Stable Vinylketene and Reactive Enophile in Cycloadditions
Danheiser, Rick L.,Sard, Howard
, p. 4810 - 4812 (1980)
(Trimethylsilyl)vinylketene has been prepared by dehydrohalogenation of (Z)-2-(trimethylsilyl)-2-butenoyl chloride and shown to be a relatively stable compound which participates in Diels-Alder reactions as a reactive diene.
Facile synthesis of diverse multisubstituted ortho-silylaryl triflates via CH borylation
Yoshida, Suguru,Shimomori, Ken,Nonaka, Takako,Hosoya, Takamitsu
supporting information, p. 1324 - 1326 (2015/11/23)
Diverse multisubstituted ortho-silylaryl triflates were efficiently synthesized from simple ortho-silylaryl triflates via iridium-catalyzed regioselective CH borylation and subsequent deborylative functionalizations. An azidoaryne precursor synthesized by this method served as a useful bis-reactive platform molecule, thus demonstrating the utility of the method for preparing diverse aromatic compounds.
