75235-71-1

Basic information

• Product Name: 2-Propanol,1-(2-benzothiazolylthio)-(9CI)
• Synonyms: 2-Propanol,1-(2-benzothiazolylthio)-(9CI)
• CAS NO: 75235-71-1
• Molecular Formula: C₁₀H₁₁NOS₂
• Molecular Weight: 225.33044
• Product Categories: BENZOTHIAZOLE
• Mol File: 75235-71-1.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Propanol,1-(2-benzothiazolylthio)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanol,1-(2-benzothiazolylthio)-(9CI)(75235-71-1)
• EPA Substance Registry System: 2-Propanol,1-(2-benzothiazolylthio)-(9CI)(75235-71-1)

Safety Data

• Hazardous Substances Data: 75235-71-1(Hazardous Substances Data)

Upstream product

• 19686-73-8 1-bromo-2-propanol 
• 149-30-4 2-Mercaptobenzothiazole 
• 75-56-9 methyloxirane 
• 23385-34-4 1-(benzothiazol-2-ylthio)propan-2-one 

Downstream Products

• 1433187-97-3 (2R)-1-(1,3-benzothiazol-2-ylsulfanyl)propan-2-yl (2R)-methoxy(phenyl)ethanoate 
• 1433187-98-4 (2R)-1-(1,3-benzothiazol-2-ylsulfanyl)propan-2-yl (2S)-methoxy(phenyl)ethanoate 
• 1433187-94-0 (S)-1-(1,3-benzothiazol-2-ylsulfanyl)propan-2-ol 
• 1433187-95-1 (R)-1-(1,3-benzothiazol-2-ylsulfanyl)propan-2-yl acetate 
• 1433187-96-2 (S)-1-(1,3-benzothiazol-2-ylsulfanyl)propan-2-yl acetate 
• 244221-77-0 (R)-1-(1,3-benzothiazol-2-ylsulfanyl)propan-2-ol 

Relevant articles and documents

Aromatic heterocyclic borate and its preparation method, use (by machine translation)

The invention relates to a hydroxyalkylation heterocyclic borate and its preparation method, use; said additive structural formula such as formula (I) or (II) shown; the invention also relates to the above-mentioned aromatic heterocyclic borate lubricating additive preparation method, the method comprises the following steps: step a, in the organic solvent and catalyst under the condition of, heterocyclic compounds and alkyl epoxide reaction, generating compounds A; make stated, in the organic solvent and catalyst under the condition of the, compound B with compound A, or by the reaction of the cyclic ethers, can be; the invention also relates to the use of alkylated heterocyclic borate fore-mentioned hydroxy. (by machine translation)

Asymmetric reduction of 1-(benzoazol-2-ylsulfanyl)propan-2-ones using whole cells of Mortierella isabellina, Debaryomyces hansenii, Geotrichum candidum and Zygosaccharomyces rouxii

Growing cells of four fungal strains were used in reduction of 1-(benzoazol-2-ylsulfanyl)propan-2-ones3a-c to corresponding (R)-(+)-1-(benzoazol-2-ylsulfanyl)propan-2-ols (R)-(+)-4a-c. All of the investi-gated yeast strains displayed a very high activity toward prochiral ketones 3a-c converting them tothe desired alcohols after relatively short reaction time (1-3.5 h). The biotransformation products wereisolated with moderate to good yields (45-89%) and in highly enantioenriched forms (94-99% ee). Ste-reoselective bioreduction of 1-(1H-benzimidazol-2-ylsulfanyl)propan-2-one 3a by D. hansenii DSM 3428growing cells provided the respective (R)-alcohol with >99% yield, in reasonable 65% isolated yield andin a highly stereoselective manner (98% ee) after 3 h of cultivation. In the same culture, bioreduction of1-(1,3-benzoxazol-2-ylsulfanyl)propan-2-one 3b led to a 76% yield, 65% isolated yield and very high 94%ee of the formed (R)-alcohol. Similar 1.5 h incubation of 1-(1,3-benzothiazol-2-ylsulfanyl)propan-2-one3c in G. candidum LOCK 105 culture resulted in the corresponding (R)-alcohol preparation in moderate45% isolated yield with excellent enantiomeric purity (99% ee).