75251-35-3

Basic information

• Product Name: 1-Phenoxy-2-propanon-diethylacetal
• CAS NO: 75251-35-3
• Molecular Weight: 224.3
• Mol File: 75251-35-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Phenoxy-2-propanon-diethylacetal(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Phenoxy-2-propanon-diethylacetal(75251-35-3)
• EPA Substance Registry System: 1-Phenoxy-2-propanon-diethylacetal(75251-35-3)

Safety Data

• Hazardous Substances Data: 75251-35-3(Hazardous Substances Data)

Upstream product

• 621-87-4 3-phenoxy-2-propanone 
• 122-51-0 orthoformic acid triethyl ester 

Downstream Products

• 81023-37-2 (E)-N-(1-Methyl-2-phenoxyethyliden)benzolamin 
• 75250-93-0 (Z)-N-(1-Methyl-2-phenoxyethyliden)benzolamin 
• 75251-36-4 2-Methyl-3-phenoxy-2-(phenylamino)propannitril 

Relevant articles and documents

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Azomethines, 1-Azaallyl Anions, and Metastable Secondary Enamines

E/Z equilibrium constants of the ketone anils 6a-s do not depend significantly on the inductive substituent effect. 1H NMR chemical shifts used for configurational classification are also effective for assignments in comparable, isomerically almost pure azomethines 6aa-pp and may be explained by the anisotropic shift model.The 1-azaallyl anions 7 prepared by deprotonation are characterized by 1H NMR spectroscopy.Kinetic and thermodynamic control of this metallation reaction result in different preferential configurations of such anions, the methanolysis of which yields metastable sec. enamines 8 by regio- and stereospecific N-protonation.It is possible to estimate further substituent parameters λd from E/Z equilibria.