75283-43-1Relevant academic research and scientific papers
Selectivity in retro-ene vs. cyclopentene rearrangements of a cis-methylvinylcyclopropane
Hudlicky,Koszyk
, p. 2487 - 2490 (2007/10/02)
The thermolytic behavior of 6β-ethenyl-1β-methyl-bicyclo [3.1.0] hexane-2-one was examined at a wide range of temperatures and with diverse catalytic surfaces. Conditions are reported to effect selectivity between the retro-ene and the cyclopentene modes of rearrangement. The synthetic scope of these transformations is indicated.
