75308-07-5Relevant academic research and scientific papers
THE BIO-TRANSFORMATION OF SOME 6-SUBSTITUTED ENT-KAUR-16-ENES BY GIBBERELLA FUJIKUROI
Alam, Muzaffar,Hanson, James R.,Sarah, Fahmi Y.
, p. 807 - 809 (2007/10/02)
Incubation of a series of 6-oxygenated ent-kaur-16-enes with Gibberella fujikuroi affords the seco ring B derivative, fujenal, and some other metabolites.
Neighbouring Group Participation in the Reduction of the Diterpenoid Fujenal
Baynham, Mark K.,Dickinson, Julia M.,Hanson, James R.,Hitchcock, Peter B.
, p. 1987 - 1990 (2007/10/02)
Hydride reduction of the aldehyde-anhydride, fujenal, proceeds first at the C-7 aldehyde.This generates a C-7 alkoxide which then participates in the reactions of the C-6 carbonyl groups.C-6 --> C-7 and C-6 --> C-19 lactones are formed.The structure of a
