75340-94-2Relevant academic research and scientific papers
Electrochemical Oxidation of Metal Dialkyl Phosphites and Their Reaction with Halogens
Romakhin,Zagumennov,Nikitin
, p. 1022 - 1026 (2007/10/03)
Electrochemical oxidation of sodium dialkyl phosphites with alkyl radicals of normal structure leads to formation of tetraalkyl pyrophosphites as the main products, while electrochemical oxidation of litium dialkyl phosphites and sodium salts with branched alkyl radicals yields tetraalkyl hypophosphates. The reaction of metal dialkyl phosphites with halogens leads to analogous results.
Photochemical Type I and II Elimination Reactions of Dialkyl (Trichloromethyl)phosphonates
Suzuki, Nobutaka,Kawai, Teruyuki,Inoue, Susumu,Sano, Naoki,Izawa, Yasuji
, p. 1421 - 1424 (2007/10/02)
Irradiation of diisobutyl, dipropyl, and diethyl (trichloromethyl)phosphonates in MeCN gave corresponding monoesters and olefins via photochemical type II elimination.In addition, products via type I elimination were obtained from diisobutyl (trichloromethyl)phosphonate and its dimethyl ester.
