753488-76-5

Basic information

• Product Name: Cyclohexene, 3-[(2,3-dimethyl-2-butenyl)oxy]- (9CI)
• Synonyms: Cyclohexene, 3-[(2,3-dimethyl-2-butenyl)oxy]- (9CI)
• CAS NO: 753488-76-5
• Molecular Formula: C12H20O
• Molecular Weight: 180.2866
• Product Categories: METHOXY
• Mol File: 753488-76-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexene, 3-[(2,3-dimethyl-2-butenyl)oxy]- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 3-[(2,3-dimethyl-2-butenyl)oxy]- (9CI)(753488-76-5)
• EPA Substance Registry System: Cyclohexene, 3-[(2,3-dimethyl-2-butenyl)oxy]- (9CI)(753488-76-5)

Safety Data

• Hazardous Substances Data: 753488-76-5(Hazardous Substances Data)

Upstream product

• 822-67-3 Cyclohex-2-enol 

Relevant articles and documents

Allyl, methallyl, prenyl, and methylprenyl ethers as protected alcohols: Their selective cleavage with diphenyldisulfone under neutral conditions

Diphenyldisulfone is a mild and efficient reagent for selective cleavage of methylprenyl (2,3-dimethylbut-2-en-1-yl), prenyl (3-methylbut-2-en1-yl), and methallyl (2-methylallyl) ethers. These reaction conditions are compatible with the presence of other protecting groups such as acetals, acetates, and allyl, benzyl, and TBDMS ethers. Exposure of 2,3-dimethylbut-2-en-1-yl and 3-methylbut-2-en1-yl ethers to diphenyldisulfone led to the formation of 2,3-dimethylbuta-1,3-diene and isoprene, respectively. 2-Methylallyl ethers undergo isomerization to 2-methylpropenyl ethers, which are easily hydrolyzed into the corresponding free alcohols and isobutyraldehyde.