75376-94-2

Upstream product

• 59481-69-5 1,1-dideuterocinnamyl alcohol 
• 10568-31-7 <αα-2H2>cinnamyl alcohol 

Downstream Products

• 75376-93-1 (αα-dideuteriocinnamyl)dimethyl-(3-phenylprop-2-ynyl)ammonium bromide 
• 50742-91-1 N-(<αα-2H2>cinnamyl)-2-hydroxy-NN-di(<2H3>methyl)anilinium bromide 
• 79833-35-5 N-(<αα-2H2>cinnamyl)-NN-di(<2H3>methyl)anilinium-2-olate 
• 1218786-08-3 C₂₃H₂₅⁽²⁾H₂NO₂S 
• 87132-50-1 1-<1,1-(2)H2>cinnamyl-1,1-dimethyl-2-(<(2)H5>phenylcarbamoyl)-hydrazinium bromide 

Relevant academic research and scientific papers

Base Catalysed Rearrangements Involving Ylide Intermediates. Part 12. The Preparation and Reactions of 2-Oxidoanilinium Ylides

2-Oxidoanilinium ylides (22) may be prepared from the corresponding quarternary salts (21) by reaction with aqueous sodium hydroxide.The ylides (22) rearrange on heating to give the products (23) of rearrangements which, on the basis of mixing exper

Base Catalysed Rearrangements involving Ylide Intermediates. Part 6. The Rearrangements of Diallyl- and Allylpropynyl-ammonium Cations in Protic Media

The base catalysed rearrangements of the cations (1d-j) in aqueous solution yield the isomeric cations (15) or the aldehydes (10) and (11), or mixtures of (15), (10), and (11).This contrasts dramatically with the transformations observed for the cations (1) in aprotic solvents.The cations (15) undergo Hofmann elimination to the naphthalenic amines (12) or (13) and (14).The methiodide of amine (13g) shows a novel consequence of restricted rotation.The n.m.r. spectrum of the methiodide shows that the two protons of the methylene group are diastereotopic.