754160-20-8Relevant academic research and scientific papers
Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction
Ulmann, Pirmin A.,Braunschweig, Adam B.,Lee, One-Sun,Wiester, Michael J.,Schatz, George C.,Mirkin, Chad A.
supporting information; experimental part, p. 5121 - 5123 (2009/12/08)
This study describes a heteroligated, hemilabile PtII-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn III-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group. The Royal Society of Chemistry 2009.
