754232-75-2Relevant articles and documents
S-Trifluoromethyl esters of thiocarboxylic acids, RC(O)SCF3
Kremlev, Mikhail M.,Tyrra, Wieland,Naumann, Dieter,Yagupolskii, Yurii L.
, p. 6101 - 6104 (2004)
S-Trifluoromethyl esters of different types of thiocarboxylic acids have been prepared in moderate to excellent yields from halide substitution reactions of the corresponding acid chlorides and tetramethylammonium trifluoromethylthiolate. C6F5C(O)SCF3 undergoes a surprising rearrangement on attempted isolation to give 4-CF 3SC6F4C(O)F, which was converted into the corresponding acid.