75437-99-9Relevant academic research and scientific papers
SULFINES IN THE OXIDATIONS OF 1,2-DITHIOLE-3-THIONES
Tamagaki, Seizo,Hotta, Kazuhiko,Kozuka, Seizi
, p. 619 - 620 (1980)
The oxidation of 1,2-dithiole-3-thiones with MCPBA or NaIO4 gives the sulfines in good yield, while the reactions with O2l, O3, NaOCl, and BPO produce 1,2-dithiole-3-ones which are formed via the sulfines as transient intermediates.
A Sulphine Mechanism for the Singlet Oxygenation of Thiones
Tamagaki, Seizo,Hotta, Kazuhiko
, p. 598 - 599 (2007/10/02)
The mechanism of the singlet oxygenation of thiones has been studied by using 1,2-benzodithiole-3-thione; the reaction was found to proceed via a sulphine but not a dioxathietan intermediate.
