75456-44-9Relevant academic research and scientific papers
Diastereoselective oxyselenylation of 1,n-diolefins utilizing PET generated [PhSeSePh]+ · as an electrophilic species: An efficient and general strategy for the synthesis of α,α'-trans-dialkyl cyclic ethers
Pandey, Ganesh,Sochanchingwung,Tiwari, Shashi Kant
, p. 1257 - 1258 (2007/10/03)
PET generated electrophilic species [PhSeSePh]+ · is found to effect stereoselective oxyselenylation of 1,n-diolefins (1) leading to a novel strategy for the synthesis of α,α'-trans-dialkyl cyclic ethers (5) in good yields.
PHENYLSELENENYL CHLORIDE AS A REAGENT FOR THE FACILE PREPARATION OF CYCLIC ETHERS FROM DIOLEFINS
Uemura, Sakae,Toshimitsu, Akio,Aoai, Toshiaki,Okano, Masaya
, p. 1533 - 1536 (2007/10/02)
Various cyclic ethers are prepared in good to excellent yields by treating diolefins with phenylselenenyl chloride in aqueous acetonitrile.This is the most facile method for organoselenium-induced formation of cyclic ethers from diolefins so far reported.
