75458-39-8Relevant academic research and scientific papers
BH3-promoted stereoselective β-lithiation of N-alkyl-2-phenylaziridines
Azzena, Ugo,Dettori, Giovanna,Pisano, Luisa,Musio, Biagia,Luisi, Renzo
scheme or table, p. 2291 - 2295 (2011/05/19)
BH3 complexes of N-alkyl-2-phenylaziridines have been synthesized and their structure and stereochemistry proved with DFT calculations and NMR experiments. It has been demonstrated that the Lewis acid complexation is able to promote a regiosele
Stereospecific Synthesis of N-Substituted cis-2-Aryl-3-alkylaziridines
Kimpe, Norbert De,Verhe, Roland,Buyck, Laurent De,Schamp, Niceas
, p. 5319 - 5325 (2007/10/02)
A convenient stereospecific synthesis of N-substituted cis-2-aryl-3-alkylaziridines is reported, by reaction of N-alkyl or N-aryl α,α-dichloroalkyl aryl ketimines with lithium aluminum hydride in ethereal medium.The mechanism involves the addition of hydr
