75466-93-2

Upstream product

• 79432-05-6 ε-carbobenzoxy-δ-hydroxy-L-lysine (normal and allo forms) 
• 501-53-1 benzyl chloroformate 
• 144090-59-5 (S)-4-((S)-4-Azido-3-hydroxy-butyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 144090-58-4 (S)-2,2-Dimethyl-4-(2-oxiranyl-ethyl)-oxazolidine-3-carboxylic acid tert-butyl ester 
• 144090-57-3 tert-butyl (S)-4-(but-3-enyl)-2,2-dimethyloxazolidine-3-carboxylate 
• 79432-14-7 (2S,5R)-2-amino-6-[(benzyloxycarbonyl)amino]-5-hydroxyhexanoic acid 
• 96261-29-9 dicarbobenzoxy-δ-hydroxy-L-lysine-lactone 
• 96359-88-5 (2S,5R)-6-[(benzyloxycarbonyl)amino]-2-[(tert-butoxycarbonyl)amino]-5-hydroxyheptanoic acid 
• 144090-61-9 (S)-4-((S)-4-Azido-3-benzyloxy-butyl)-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 

Downstream Products

• 103758-70-9 (+/-)-N-(threo-2,6-bis-benzyloxycarbonylamino-5-hydroxy-hexanoyl)-glycine amide 
• 103758-62-9 optically inactive N-((2Ξ)-threo-2,6-bis-benzyloxycarbonylamino-5-hydroxy-hexanoyl)-Ξ-alanine amide 
• 504-91-6 D-glycero-D-guloheptonic acid 
• 113455-38-2 (+/-)-threo-2,6-bis-benzyloxycarbonylamino-5-hydroxy-hexanoic acid amide 
• 115829-38-4 (+/-)-threo-2,6-bis-benzyloxycarbonylamino-5-hydroxy-hexanoic acid hydrazide 
• 504-91-6 DL-erythro-5-hydroxy-lysine 
• 113455-38-2 (+/-)-erythro-2,6-bis-benzyloxycarbonylamino-5-hydroxy-hexanoic acid amide 
• 115829-38-4 (+/-)-erythro-2,6-bis-benzyloxycarbonylamino-5-hydroxy-hexanoic acid hydrazide 
• 75466-98-7 dicarbobenzoxy-δ-hydroxy-L-lysyl-O-t-butylglycyl-O-<2-O-(2,3,4,6-tetra-O-benzyl) α-D-glucopyranosyl>-3,4,6-tri-O-acetyl-β-D-galactopyranoside 
• 75466-99-8 {(2S,5R)-2,6-Bis-benzyloxycarbonylamino-5-[(2R,3R,4S,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-3-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexanoylamino}-acetic acid 
• 75477-74-6 {(2S,5R)-2,6-Bis-benzyloxycarbonylamino-5-[(2R,3R,4S,5R,6R)-4,5-dihydroxy-6-hydroxymethyl-3-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-hexanoylamino}-acetic acid 
• 75466-96-5 4-Oxo-pentanoic acid (2R,3R,4S,5S,6R)-4,5-diacetoxy-6-acetoxymethyl-2-[(1R,4S)-4-benzyloxycarbonylamino-1-(benzyloxycarbonylamino-methyl)-4-(tert-butoxycarbonylmethyl-carbamoyl)-butoxy]-tetrahydro-pyran-3-yl ester 
• 75466-97-6 dicarbobenzy-δ-hydroxy-L-lysyl-O-t-butylglycyl-O-3,4,6-tri-O-acetyl-β-D-galactopyranoside 
• 79432-06-7 dicarbobenzoxy-δ-hydroxy-L-lysylglycine t-butyl ester 

Relevant academic research and scientific papers

A Strategy Towards the Stereoselective Synthesis of 5-Hydroxylysine

A stereoselective synthesis of 5-hydroxylysine is described in which the α-stereogenic centre is generated by a Schoellkopf amino acid synthesis, and the ethanolamine structure is obtained via Sharpless aminohydroxylation from an olefin moiety. The reactions and their selectivities are studied.

Total Synthesis and Absolute Configuration of Bengamide A

The first total synthesis of the novel marine natural product, bengamide A 1 is described, revealing the absolute configuration of this compound.

SYNTHESIS OF O-(2-O-α-D-GLUCOPYRANOSYL)-β-D-GALACTOPYRANOSIDE OF OPTICALLY PURE δ-HYDROXY-L-LYSYLGLYCINE AND δ-HYDROXY-L-LYSYLGLYCYL-L-GLUTAMYL-L-ASPARATYLGLYCINE. COMPONENTS OF THE GLOMERULAR BASEMENT MEMBRANE

The application of the levulinyl group as a temporary blocking group for the 2-OH function of galactose proved to be very efficient not only for the introduction of a β- linkage between galactose and the optically pure δ-hydroxy-L-lysylglycine, but also t