75476-41-4Relevant academic research and scientific papers
Unexpected diels-Alder/carbonyl-ene cascade toward the biomimetic synthesis of chloropupukeananin
Suzuki, Takahiro,Miyajima, Yuria,Suzuki, Kaname,Iwakiri, Kanako,Koshimizu, Masaki,Hirai, Go,Sodeoka, Mikiko,Kobayashi, Susumu
supporting information, p. 1748 - 1751 (2013/07/05)
The biomimetic synthesis of the advanced model compound of chloropupukeananin has been achieved. The present synthesis features an unexpected enantiomer-differentiating Diels-Alder/carbonyl-ene cascade under high-pressure conditions and a base-promoted migration of the salicyl group.
Effect of an Alkynyl Group on the Regio- and Stereochemistry of the Ring Opening of 1,2-Epoxides. Ring-Opening Reactions of 1-Ethenyl-1,2-epoxycyclohexane
Battistini, Carlo,Crotti, Paolo,Macchia, Franco
, p. 434 - 438 (2007/10/02)
The regio- and stereochemistry of the ring-opening reactions of 1-ethenyl-1,2-epoxycyclohexane (1) under acidic conditions have been examined.The reactions were almost completely regiospecific, giving mainly products arising from attack by nucleophile on
