75476-57-2Relevant academic research and scientific papers
Rhodium-catalyzed alkenylation of nitriles via silicon-assisted C-CN bond cleavage
Kita, Yusuke,Tobisu, Mamoru,Chatani, Naoto
supporting information; experimental part, p. 1864 - 1867 (2010/10/02)
Rhodium-catalyzed Mizoroki-Heck type reaction of nitriles via the cleavage of C-C bonds is described. Orthogonal and iterative functionalizations of arenes were also demonstrated by combining the present and conventional halide-based cross-coupling reacti
Highly selective dehydrogenative silylation of alkenes catalyzed by rhenium complexes
Jiang, Yanfeng,Blacque, Olivier,Fox, Thomas,Freeh, Christian M.,Berke, Heinz
experimental part, p. 2121 - 2128 (2009/09/30)
Rhenium(I) complexes of type [ReBr2(L)(NO)(PR3) 2] (L = H2 (1), CH3CN (2), and ethylene (3); R = iPr (a) and cyclohexyl (Cy; b)) catalyze dehydrogenative silylation of alkenes in a highly selective ma
