755016-01-4

Upstream product

• 7103-09-5 4-but-1-enylmagnesium bromide 
• 755015-99-7 (R)-2-t-butyldiphenylsilyloxymethyl-2-undecyloxirane 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 755015-98-6 (S)-1-(t-butyldiphenylsilyloxy)-2-chloromethyl-2-tridecanol 
• 755015-88-4 (S)-4-dichloromethyl-2,2-dimethyl-4-undecyl-1,3-dioxolane 
• 755015-95-3 (S)-4-chloromethyl-2,2-dimethyl-4-undecyl-1,3-dioxolane 
• 755015-89-5 (S)-2-dichloromethyltridecane-1,2-diol 
• 755015-97-5 (S)-2-chloromethyltridecane-1,2-diol 
• 847658-59-7 (S)-4-dichloromethyl-2,2-dimethyl-4-(3-undecen-1-yl)-1,3-dioxolane 
• 755016-00-3 (R)-2-undecyloxirane-2-carbaldehyde 
• 755015-91-9 ethyl (S)-3-(4-dichloromethyl-2,2-dimethyl-1,3-dioxolan-4-yl)propanoate 
• 755015-94-2 (S)-3-(4-dichloromethyl-2,2-dimethyl-1,3-dioxolane-4-yl)propanal 
• 487001-25-2 (2S)-2,3-epoxy-2-undecanylpropan-1-ol 
• 36326-39-3 Ethyl 4,5-O-isopropylidene-(S)-4,5-dihydroxypentanoate 

Downstream Products

• 755016-02-5 (R)-6-(t-butyldiphenylsiloxymethyl)-6-undecyltetrahydropyran-2-one 

Relevant academic research and scientific papers

Synthesis of (R)-(+)-tanikolide through stereospecific C-H insertion reaction of dichlorocarbene with optically active secondary alcohol derivatives

Stereospecific α C-H insertion reaction of protected chiral 1,2-glycols, (S)-1,2-isopropylidenedioxytridecane (3) and ethyl (S)-4,5-isopropylidenedioxy-pentanoate (4), prepared from (R)-glyceraldehyde acetonide (2), with dichlorocarbene generated from CHC