75503-34-3Relevant articles and documents
Oxygen-transfer Reactions in Platinum Metal Complexes of Nitric Oxide and Sulphur Dioxide
Bhaduri, Sumit,Johnson, Brian F. G.,Khair, Abdul,Ghatak, I.,Mingos, D. M. P.
, p. 1572 - 1576 (1980)
The reactions of SO2 with and NO with have been shown to result in the formation of and , which arise from ready oxygen-transfer reactions.A compound which analyses correctly for has also been isolated from these reactions and is formulated as an insertion product on the basis of i.r. and chemical studies.The reaction of with SO2 proceeds in a quite different fashion and gives an SO2 adduct which has both a linear and a bent NO ligand.This complex is readily oxidised to the corresponding sulphato-complex in air.
Hydrolysis Reaction of . Crystal Structures of *H2O and 2>*5CHCl3
Ginn, Vanessa C.,Kelly, Paul F.,Papadimitriou, Christos,Slawin, Alexandra M. Z.,Williams, David J.,Woolins, J. Derek
, p. 1805 - 1810 (2007/10/02)
The reaction of with water in dichloromethane gives the compounds *H2O 1 and 2>*5CHCl3 2 which have been characterised by multielement NMR spectroscopy and X-ray crystallography.The mononuclear compound 1 has tetrahedrally distorted square-planar co-ordination of the platinum by three phosphines and the sulfur atom of the sulfite with trans angles of 160.4(1) and 161.2(1) deg.The binuclear complex 2 contains a six-membered Pt2S2O2 ring in a chair conformation with each platinum being co-ordinated by two phosphines and a sulfur and oxygen atom of the different SO3(2-) ligands.P hosphorus-31 NMR studies show that the reaction of Ag2SO3 with gives 1 and 2 or simple O,O'-complexes depending on the nature of PR3.
