75534-56-4

Upstream product

• 75597-72-7 (+)-4-(carboxymethyl)-5-oxahexacyclo<7.2.1.0^2,8.0^3,7.0^4,11.0^6,10>dodecane 
• 76374-20-4 C₁₉H₂₂O₅S 
• 75534-46-2 C₁₃H₁₂O₄ 
• 75534-45-1 methyl 3,6-dioxo-endo-tricyclo[6.2.1.0^2,7]undeca-4,9-diene-2-carboxylate 
• 75534-48-4 4-(cyanomethyl)-5-oxahexacyclo<7.2.1.0^2,8.0^3,7.0^4,11.0^6,10>dodecane 
• 75534-47-3 9-(hydroxymethyl)pentacyclo<5.4.0.0^2,6.0^3,10.0^5,9>undecane-8,11-diol 
• 3958-79-0 methyl 3,6-dioxocyclohexa-1,4-diene-1-carboxylate 
• 2150-46-1 Methyl 2,5-dihydroxybenzoate 
• 75534-55-3 (+)-4-(2-hydroxyethyl)-5-oxahexacyclo<7.2.1.0^2,8.0^3,7.0^4,11.0^6,10>dodecane 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant academic research and scientific papers

Synthesis and absolute configuration of the first optically active organic molecule with T symmetry: (-)-1,3,5,7-tetrakis3-trishomocubanyl)acetoxy>methyl>adamantane

By starting from the Diels-Alder adduct 12 between 2-(methoxycarbonyl)-1,4-benzoquinone (11) and cyclopentadiene, the modified Barborak synthesis of D3-trishomocubane afforded (-)-2-(1S,3S,5R,6S,8R,10R)-D3-trishomocubaneacetic acid (19) whose esterification with 1,3,5,7,-tetrakis(hydroxymethyl)adamantane (27) gave (-)-28, the first T symmetric organic molecule with known absolute configuration.