75544-36-4Relevant articles and documents
Bromination of Enamines from Methyl Isopropyl Ketone. III. Bromination of 2-(1-Pyrrolidinyl)-3-methyl-1-butene
Carlson, Rolf
, p. 157 - 160 (2007/10/02)
The reaction of 2-(1-pyrrolidinyl)-3-methyl-1-butene with elemental bromine was studied under varying conditions.Reaction in pentane solution followed by hydrolysis afforded high yields of the expected halomethyl ketone, 1-bromo-3-methyl-2-butanone.Reaction in dichloromethane gave several by-products.Mechanisms for the by-product forming reactions are suggested and experimental observations supporting the proposed mechanisms are given.