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Relevant academic research and scientific papers

In vitro inhibition of human erythrocyte glutathione reductase by some new organic nitrates

Glutathione reductase (GR), is responsible for the existence of GSH molecule, a crucial antioxidant against oxidative stress reagents. The antimalarial activities of some redox active compounds are attributed to their inhibition of antioxidant flavoenzyme

1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate: An efficient reagent for synthesis of Β-nitrato alcohols

A simple and efficient method for the ring opening of epoxides to-hydroxy nitrates has been achieved in the presence of ammonium nitrate and 1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate.

Tetranitromethane as an efficient reagent for the conversion of epoxides into β-hydroxy nitrates

A convenient regioselective method for the preparation of β-hydroxy nitrates based on the ring opening reaction of epoxides by tetranitromethane in the presence of triethylamine is described. A series of substituted β-hydroxy nitrates were obtained in high yields under mild conditions.

Efficient regio- and stereoselective conversions of oxiranes and aziridines into β-(nitrooxy)-substituted alcohols and amines by using bismuth nitrate

Oxiranes and aziridines efficiently undergo ring opening with bismuth nitrate at room temperature to furnish the corresponding β-(nitrooxy)- substituted alcohols and amines respectively. The conversions are highly regio- and stereoselective and afford the

Bismuth(III) salts mediated regioselective ring opening of epoxides: an easy route to halohydrins and β-hydroxy nitrates

The ring opening of various epoxides was achieved under mild conditions using bismuth(III) salts. Halohydrins and β-hydroxy nitrates were efficiently obtained from the corresponding 5α,6α-, 2α,3α-, and 5β,6β-epoxysteroid using BiCl3, BiBr3

Micellar media for the efficient ring opening of epoxides with CN-, N3-, NO3-, NO2-, SCN-, Cl- and Br- catalyzed with Ce(OTf)4

Micellar media are introduced for the efficient ring opening of epoxides with sodium salts of nucleophiles such as CN, N3-, NO3-, NO2, SCN, Br and Cl-, catalyzed with Ce(OTf)4. This method is an efficient procedure for the synthesis of different β-substituted alcohols under mild reaction conditions. The reaction with SCN- is an easy procedure for the high yielding preparation of epoxy sulfides.

Iron(III) trifluoroacetate as an efficient catalyst for solvolytic and nonsolvolytic nucleophilic ring opening of epoxides

Iron(III) trifluoroacetate was used as an efficient and nonhygroscopic catalyst for the alcoholysis, hydrolysis, and acetolysis of epoxides. The addition of chloride, bromide, iodide, and nitrate ions to epoxides to produce the corresponding 2-halo and 2-nitratoalkanols and also the conversion of epoxides to acetonides and thiiranes were also performed efficiently in the presence of this catalyst.

Nitrate ester derivatives from epoxides using CAN: Efficient preparation of key intermediates in the synthesis of 4-alkoxytrinems

A regio and stereoselective opening reaction of epoxide with CAN (0.5 equivalents) in aprotic solvents is described. This novel reaction allowed the preparation of versatile nitrate estec derivatives as useful intermediates in the synthesis of trinems wid

Ceric ammonium nitrate: A mild and efficient reagent for conversion of epoxides to β-nitrato alcohols

Catalytic amount of Ce(IV) as ceric ammonium nitrate (CAN) alone or in the presence of excess nitrate ion reacts smoothly and efficiently with epoxides under mild conditions to produce the corresponding β-nitrato alcohols in good to excellent yields.

Kinetics and Mechanism of Reaction of Aryl Oxiranes with Dinitrogen Pentoxide in Dichloromethane

4-X-Phenyloxiranes (X = H, Cl, CF3, NO2) in dichloromethane react with N2O5 to give 1-(4-X-phenyl)ethane-1,2-diol dinitrates and with HNO3 to give 2-(4-X-phenyl)-2-nitroethanols.Both reactions give quantitative yields.Kinetics of both reactions, mostly at