75567-31-6Relevant academic research and scientific papers
Solvolysis of specifically deuterated 7-chloro- and 7-bromo-exo-2-norbornyl brosylates; unusually large γ-kinetic isotope effects in the absence of ?-participation
Werstiuk, Nick Henry,Timmins, George,Cappelli, Frank Peter
, p. 1738 - 1750 (2007/10/02)
A series of specifically deuterated syn-7-chloro-, anti-7-chloro-, syn-7-bromo-, and anti-7-bromo-exo-2-norbornyl brosylates have been prepared and solvolyzed in NaOAc-buffered 80:20 EtOH-H2O.For solvolysis at 25 deg C the γ-kinetic isotope effects (KIE's
