755752-92-2Relevant articles and documents
A family of low-molecular-weight organogelators based on Nα,Nε-diacyl-l-lysine: effect of alkyl chains on their organogelation behaviour
Suzuki, Masahiro,Yumoto, Mariko,Shirai, Hirofusa,Hanabusa, Kenji
, p. 10395 - 10400 (2008)
A family of low-molecular-weight organogelators based on Nα,Nε-diacyl-l-lysine was synthesized by acylation of Nε-dodecyl-l-lysine with acyl chlorides through the one-pot synthetic procedure and their organogelation properties were examined. These compounds functioned as an organogelator; especially, l-lysine derivatives possessing the branched alkyl groups are a better organogelation property. The NMR and IR studies demonstrate that the organogelation occurred through hydrogen bonding interactions between the amide groups and between the carboxy groups.
New Low-Molecular-Mass Gelators Based on L-Lysine: Amphiphilic Gelators and Water-Soluble Organogelators
Suzuki, Masahiro,Yumoto, Mariko,Kimura, Mutsumi,Shirai, Hirofusa,Hanabusa, Kenji
, p. 1 - 10 (2007/10/03)
The new L-lysine alkali-metal salts 1-5 (M+= Na+ and K+) with different alkyl groups at the Na-position were easily synthesized, and their hydro- and organogelation properties were investigated. All compounds were H20-soluble, and some salts, especially the potassium salts, functioned as a hydrogenator that could gel water below 2 wt-%. These salts also had organogelation abilities for many organic solvents.