75591-39-8Relevant academic research and scientific papers
Solid sodium hydroxide - THF, convenient system for synthesis esters of glycidic acids by darzens condensation
Gadaj,Kowalkowska,Jonczyk
, p. 577 - 584 (2008/09/19)
Isopropyl- and tert-butylchloroacetate react with carbonyl compounds in the presence of powdered sodium hydroxide in THF, without a catalyst, giving substituted glycidates. The process is applied for preparation of glycidates from ketones, hitherto unavailable by phase-transfer catalyzed Darzens condensation.
Mass Spectrometric Studies of t-Butyl β-Phenylglycidates
Bansal, R. K.,Sethi, K.,Bachelor, F. W.
, p. 515 - 517 (2007/10/02)
The effect of β-substitution on the fragmentation pattern of t-butyl β-phenylglycidates (I-VII) has been elucidated.Unlike ethyl β-phenylglycidates it has been found that the migration of t-butoxy group does not take place in the esters (I-VII).Structures
